Showing posts with label Thermodynamics. Show all posts
Showing posts with label Thermodynamics. Show all posts

Friday 1 May 2015

Thermodynamics Questions and Answers

Thermodynamics Questions and Answers

1. Which of the following variables controls the
physical properties of a perfect gas
(a) pressure
(b) temperature
(c) volume
(d) all of the above
(e) atomic mass.
Ans: d
2. Which of the following laws is applicable for the
behavior of a perfect gas
(a) Boyle's law
(b) Charles'law
(c) Gay-Lussac law
(d) all of the above
(e) Joule's law.
Ans: d
3. The unit of temperature in S.I. units is
(a) Centigrade
(b) Celsius
(c) Fahrenheit
(d) Kelvin
(e) Rankine.
Ans: d
4. The unit of mass in S.I. units is
(a) kilogram
(b) gram
(c) tonne
(d) quintal
(e) newton.
Ans: a
5. The unit of time in S.I. units is
(a) second
(b) minute
(c) hour
(d) day
(e) year.
Ans: a
6. The unit of length in S.I. units is
(a) meter
(b) centimeter
(c) kilometer
(d) millimeter.
Ans: a
7. The unit of energy in S.I. units is
(a) watt
(b) joule
(c) joule/s
(d) joule/m
(e) joule m.
Ans: b
8. According to Gay-Lussac law for a perfect gas,
the absolute pressure of given mass varies directly
as
(a) temperature
(b) absolute
(c) absolute temperature, if volume is kept constant
(d) volume, if temperature is kept constant
(e) remains constant,if volume and temperature are
kept constant.
Ans: c
9. An ideal gas as compared to a real gas at very
high pressure occupies
(a) more volume
(b) less volume
(c) same volume
(d) unpredictable behaviour
(e) no such correlation.
Ans: a
10. General gas equation is
(a) PV=nRT
(b) PV=mRT
(d) PV = C
(c) PV=KiRT
(e) Cp-Cv = Wj
Ans: b
11. According to Dalton's law, the total pres sure of
the mixture of gases is equal to
(a) greater of the partial pressures of all
(b) average of the partial pressures of all
(c) sum of the partial pressures of all
(d) sum of the partial pressures of all divided by
average molecular weight
(e) atmospheric pressure.
Ans: c
12. Which of the following can be regarded as gas
so that gas laws could be applicable, within the
commonly encountered temperature limits.
(a) 02, N2, steam, C02
(b) Oz, N2, water vapour
(c) S02, NH3, C02, moisture
(d) 02, N2, H2, air
(e) steam vapours, H2, C02.
Ans: d
13. The unit of pressure in S.I. units is
(a) kg/cm2
(b) mm of water column
(c) pascal
(d) dynes per square cm
(e) bars
Ans: c
14. A closed system is one in which
(a) mass does not cross boundaries of the system,
though energy may do so
(b) mass crosses the boundary but not the energy
(c) neither mass nor energy crosses the
boundaries of the system
(d) both energy and mass cross the boundaries of
the system
(e) thermodynamic reactions take place.
Ans: a
15. Temperature of a gas is produced due to
(a) its heating value
(b) kinetic energy of molecules
(c) repulsion of molecules
(d) attraction of molecules
(e) surface tension of molecules.
Ans: b
16. According to kinetic theory of gases, the
absolute zero temperature is attained when
(a) volume of the gas is zero
(b) pressure of the gas is zero
(c) kinetic energy of the molecules is zero
(d) specific heat of gas is zero
(e) mass is zero.
Ans: c
17. Kinetic theory of gases assumes that the
collisions between the molecules are
(a) perfectly elastic
(b) perfectly inelastic
(c) partly elastic
(d) partly inelastic
(e) partly elastic and partly inelastic.
Ans: a
18. The pressure'of a gas in terms of its mean
kinetic energy per unit volume E is equal to
(a) E/3
(b) E/2
(c) 3E/4
(d)2E/3
(e) 5E/4.
Ans: d
19. Kinetic energy of the molecules in terms of
absolute temperature (T) is proportional to
(a) T
(b) j
(c) J2
(d) Vr
(e) 1/Vr.
Ans: a
20. Superheated vapour behaves
(a) exactly as gas
(b) as steam
(c) as ordinary vapour
(d) approximately as a gas
(e) as average of gas and vapour.
Ans: d
21. Absolute zero pressure will occur
(a) at sea level
(b) at the center of the earth
(c) when molecular momentum of the system
becomes zero
(d) under vacuum conditions
(e) at a temperature of - 273 °K
Ans: c
22. No liquid can exist as liquid at
(a) - 273 °K
(b) vacuum
(c) zero pressure
(d) centre of earth
(e) in space.
Ans: c
23. The unit of power in S.I. units is
(a) newton
(b) pascal
(c) erg
(d) watt
(e) joule.
Ans: d
24. The condition of perfect vacuum, i.e., absolute
zero pressure can be attained at
(a) a temperature of - 273.16°C
(b) a temperature of 0°C
(c) a temperature of 273 °K
(d) a negative pressure and 0°C temperature
(e) can't be attained.
Ans: a
25. Intensive property of a system is one whose
value
(a) depends on the mass of the system, like volume
(b) does not depend on the mass of the system, like
temperature, pressure, etc.
(c) is not dependent on the path followed but on the
state
(d) is dependent on the path followed and not on the
state
(e) remains constant.
Ans: b
26. Specific heat of air at constant pressure is equal
to
(a) 0.17
(b) 0.21
(c) 0.24
(d) 1.0
(e) 1.41
Ans: c
27. Characteristic gas constant of a gas is equal to
(a) C/Cv
(b) Cv/Cp
(c) Cp - Cv
(d) Cp + Cv
(e) Cp x Cv
Ans: c
28. The behaviour of gases can be fully determined
by
(a) 1 law
(b) 2 laws
(c) 3 laws
(d) 4 laws
Ans: d
29. The ratio of two specific heats of air is equal to
(a) 0.17
(b) 0.24
(c) 0.1
(d) 1.41
(e) 2.71.
Ans: d
30. Boyle's law i.e. pV = constant is applicable to
gases under
(a) all ranges of pressures
(b) only small range of pressures
(c) high range of pressures
(d) steady change of pressures
(e) atmospheric conditions.
Ans: b
31. Which law states that the internal energy of a
gas is a function of temperature
(a) Charles' law
(b) Joule's law
(c) Regnault's law
(d) Boyle's law
(e) there is no such law.
Ans: b
32. The same volume of all gases would represent
their
(a) densities
(b) specific weights
(c) molecular weights
(d) gas characteristic constants
(e) specific gravities.
Ans: c
33. Which law states that the specific heat of a gas
remains constant at all temperatures and pressures
(a) Charles' Law
(b) Joule's Law
(c) Regnault's Law
(d) Boyle's Law
(e) there is no such law.
Ans: c
34. An open system is one in which
(a) mass does not cross boundaries of the system,
though energy may do so
(b) neither mass nor energy crosses the
boundaries of the system
(c) both energy and mass cross the boundaries of
the system
(d) mass crosses the boundary but not the energy
(e) thermodynamic reactions do not occur.
Ans: c
35. According to which law, all perfect gases
change in volume by l/273th of their original volume
at 0°C for every 1°C change in temperature when
pressure remains constant
(a) Joule's law
(b) Boyle's law
(c) Regnault's law
(d) Gay-Lussac law
(e) Charles' law.
Ans: e
36. Gases have
(a) only one value of specific heat
(b) two values of specific heat
(c) three values of specific heat
(d) no value of specific heat
(e) under some conditions one value and
sometimes two values of specific heat.
Ans: b
37. According to Avogadro's Hypothesis
(a) the molecular weights of all the perfect gases
occupy the same volume under same conditions of
pressure and temperature
(b) the sum of partial pressure of mixture of two
gases is sum of the two
(c) product of the gas constant and the molecular
weight of an ideal gas is constant
(d) gases have two values of specific heat
(e) all systems can be regarded as closed systems.
Ans: a
38. Extensive property of a system is one whose
value
(a) depends on the mass of the system like volume
(b) does not depend on the mass of the system, like
temperature, pressure, etc.
(c) is not dependent on the path followed but on the
state
(d) is dependent on the path followed and not on the
state
(e) is always constant.
Ans: a
39. Work done in a free expansion process is
(a) + ve
(b) -ve
(c) zero
(d) maximum
(e) minimum.
Ans: c
40. The statement that molecular weights of all
gases occupy the same volume is known as
(a) Avogadro's hypothesis
(b) Dalton's law
(c) Gas law
(d) Law of thermodynamics
(e) Joule's law.
Ans: a
41. To convert volumetric analysis to gravimetric
analysis, the relative volume of each constituent of
the flue gases is
(a) divided by its molecular weight
(b) multiplied by its molecular weight
(c) multiplied by its density
(d) multiplied by its specific weight
(e) divided by its specific weight.
Ans: b
42. If a gas is heated against a pressure, keeping
the volume constant, then work done will be equal
to
(a) + v
(b) - ve
(c) zero
(d) pressure x volume
(e) any where between zero and infinity.
Ans: c
43. An isolated system is one in which
(a) mass does not cross boundaries of the system,
though energy may do so
(b) neither mass nor energy crosses the
boundaries of the system
(c) both energy and mass cross the boundaries of
the system
(d) mass crosses the boundary but not the energy
(e) thermodynamic reactions do not occur.
Ans: b
44. Properties of substances like pressure,
temperature and density, in thermodynamic
coordinates are
(a) path functions
(b) point functions
(c) cyclic functions
(d) real functions
(e) thermodynamic functions.
Ans: b
45. Which of the following quantities is not the
property of the system
(a) pressure
(b) temperature
(c) specific volume
(d) heat
(e) density.
Ans: d
46. According to Avogadro's law, for a given
pressure and temperature, each molecule of a gas
(a) occupies volume proportional to its molecular
weight
(b) occupies volume proportional to its specific
weight
(c) occupies volume inversely proportional to its
molecular weight
(d) occupies volume inversely proportional to its
specific weight
(e) occupies same volume.
Ans: e
47. Mixture of ice and water form a
(a) closed system
(b) open system
(c) isolated system
(d) heterogeneous system
(e) thermodynamic system.
Ans: d
48. Which of the following is the property of a
system
(a) pressure and temperature
(b) internal energy
(c) volume and density
(d) enthalpy and entropy
(e) all of the above.
Ans: e
49. On weight basis, air contains following parts of
oxygen
(a) 21
(b) 23
(c) 25
(d) 73
(e) 79.
Ans: b
50. Which of the following is not the intensive
property
(a) pressure
(b) temperature
(c) density
(d) heat
(e) specific volume.
Ans: d
51. Which of the following items is not a path
function
(a) heat
(b) work
(c) kinetic energy
(d) vdp
(e) thermal conductivity.
Ans: e
52. Work done in an adiabatic process between a
given pair of end states depends on
(a) the end states only
(b) particular adiabatic process
(c) the value of index n
(d) the value of heattransferred
(e) mass of the system.
Ans: a
53. Heat and work are
(a) point functions
(b) system properties
(c) path functions
(d) intensive properties
(e) extensive properties.
Ans: c
54. Which of the following parameters is constant
for a mole for most of the gases at a given
temperature and pressure
(a) enthalpy
(b) volume
(c) mass
(d) entropy
(e) specific volume.
Ans: b
55. The value of n = 1 in the polytropic process
indicates it to be
(a) reversible process
(b) isothermal process
(c) adiabatic process
(d) irreversible process
(e) free expansion process.
Ans: b
56. Solids and liquids have
(a) one value of specific heat (ft) two values of
specific heat
(c) three values of specific heat
(d) no value of specific heat
(e) one value under some conditions and two
values under other conditions.
Ans: a
57. A perfect gas at 27°C is heated at constant
pressure till its volume is double. The final
temperature is
(a) 54°C
(b) 327°C
(c)  108°C
(d) 654°C
(e) 600°C
Ans: b
58. Curve A in Fig. 1.1 compared to curves B and C
shows the following type of expansion
(a) pV"=C
(b) isothermal
(c) adiabatic
(d) free expansion
(e) throttling.
Ans: b
59. If value of n is infinitely large in a polytropic
process pV" = C, then the process is known as
constant
(a) volume
(b) pressure
(c) temperature
(d) enthalpy
(e) entropy.
Ans: a
60. The index of compression n tends to reach ratio
of specific heats y when
(a) flow is uniform and steady
(b) process is isentropic
(c) process is isothermal
(d) process is isentropic and specific heat does not
change with temperature
(e) process is isentropic and specific heat changes
with temperature.
Ans: d
61. Change in enthalpy of a system is the heat
supplied at
(a) constant pressure
(b) constant temperature
(c) constant volume
(d) constant entropy
(e) N.T.P. condition.
Ans: a
62. The term N.T.P. stands for
(a) nominal temperature and pressure
(b) natural temperature and pressure
(c) normal temperature and pressure
(d) normal thermodynamic practice
(e) normal thermodynamic pressure.
Ans: c
63. A heat exchange process in which the product of
pressure and volume remains constant is known as
(a) heat exchange process
(b) throttling process
(c) isentropic process
(d) adiabatic process
(e) hyperbolic process.
Ans: e
64. In an isothermal process, the internal energy of
gas molecules
(a) increases
(b) decreases
(c) remains constant
(d) may increase/decrease depending on the
properties of gas
(e) shows unpredictable behaviour.
Ans: c
65. Zeroth law of thermodynamics
(a) deals with conversion of mass and energy
(b) deals with reversibility and irreversibility of
process
(c) states that if two systems are both in
equilibrium with a third system, they are in thermal
equilibrium with each other
(d) deals with heat engines
(e) does not exist.
Ans: c
66. If a certain amount of dry ice is mixed with
same amount of water at 80°C, the final
temperature of mixture will be
(a) 80°C
(b) 0°C
(c) 40°C
(d) 20°C
(e) 60°C.
Ans: b
67. The basis for measuring thermodynamic
property of temperature is given by
(a) zeroth law of thermodynamics
(b) first law of thermodynamics
(c) second law of thermodynamics
(d) third law of thermodynamics
(e) Avogadro's hypothesis.
Ans: a
68. One watt is equal to
(a) 1 Nm/s
(b) 1 N/mt
(c) 1 Nm/hr
(d) 1 kNm/hr
(e) 1 kNm/mt.
Ans: a
69. Work done is zero for the following process
(a) constant volume
(b) free expansion
(c) throttling
(d) all Of the above
(e) none of the above.
Ans: d
70. For which of the following substances, the gas
laws can be used with minimum error
(a) dry steam
(b) wet steam
(c) saturated steam
(d) superheated steam
(e) steam at atmospheric pressure.
Ans: d
71. In a non-flow reversible process for which p =
(- 3V+ 15) x 105N/m2,V changes from 1 m to 2
m3. The work done will be about
(a) 100 xlOO5 joules
(b) lxlO5 joules
(c) 10 xlO5 joules
(d) 10 xlO5 kilo joules
(e) 10xl04ki\ojoules.
Ans: c
72. The value of the product of molecular weight and
the gas characteristic constant for all the gases in
M.K.S. unit is
(a) 29.27 kgfm/mol°K
(b) 8314kgfm/mol°K
(c) 848kgfm/mol°K
(d) 427kgfm/mol°K
(e) 735 kgfm/mol°K.
Ans: c
73. On volume basis, air contains following parts of
oxygen
(a) 21
(b) 23
(c) 25
(d) 77
(e) 79.
Ans: a
74. Universal gas constant is defined as equal to
product of the molecular weight of the gas and
(a) specific heat at constant pressure
(b) specific heat at constant volume
(c) ratio of two specific heats
(d) gas constant
(e) unity.
Ans: d
75. The value of the product of molecular weight and
the gas characteristic constant for all the gases in
S.I. units is
(a) 29.27 J/kmol°K
(b) 83.14J/kmol°K
(c) 848J/kmol°K
(d) All J/kmol °K
(e) 735 J/kmol °K.
Ans: b
76. For which of the following substances, the
internal energy and enthalpy are the functions of
temperature only
(a) any gas
(b) saturated steam
(c) water
(d) perfect gas
(e) superheated steam.
Ans: d
77. In a free expansion process
(a) work done is zero
(b) heat transfer is zero
(c) both (a) and (b) above
(d) work done is zero but heat increases
(e) work done is zero but heat decreases.
Ans: c
78. If a gas vapour is allowed to expand through a
very minute aperture, then such a process is known
as
(a) free expansion
(b) hyperbolic expansion
(c) adiabatic expansion
(d) parabolic expansion
(e) throttling.
Ans: e
79. The specific heat of air increases with increase
in
(a) temperature
(b) pressure
(c) both pressure and temperature
(d) variation of its constituents
(e) air flow
Ans: a
80. If a fluid expands suddenly into vacuum through
an orifice of large dimension, then such a process is
called
(a) free expansion
(b) hyperbolic expansion
(c) adiabatic expansion
(d) parabolic expansion
(e) throttling.
Ans: a
81. Which of the following processes are
thermodynamically reversible
(a) throttling
(b) free expansion
(c) constant volume and constant pressure
(d) hyperbolic and pV = C
(e) isothermal and adiabatic.
Ans: e
82. Which of the following processes is irreversible
process
(a) isothermal
(b) adiabatic
(c) throttling
(d) all of the above
(e) none of the above.
Ans: c
83. In order that a cycle be reversible, following
must be satisfied
(a) free expansion or friction resisted expansion/
compression process should not be encountered
(b) when heat is being absorbed, temperature of hot
source and working sub¬stance should be same
(c) when beat is being rejected, temperature of cold
source and working sub-stance should be same
(d) all of the above
(e) none of the above.
Ans: d
84. For a thermodynamic process to be reversible,
the temperature difference between hot body and
working substance should be
(a) zero
(b) minimum
(d) maximum
(d) infinity
(e) there is no such criterion.
Ans: a
85. Minimum work in compressor is possible when
the value of adiabatic index n is equal to
(a) 0.75
(b) 1
(c) 1.27
(d) 1.35
(e) 2.
Ans: b
86. Molecular volume of any perfect gas at 600 x
103 N/m2 and 27°C will be
(a) 4.17m3/kgmol
(b) 400 m3/kg mol
(c) 0.15 m3/kg mol
(d) 41.7 m3/kg mol
(e) 417m3/kgmol.
Ans: a
87. A gas is compressed in a cylinder by a movable
piston to a volume one-half its original volume.
During the process 300 kJ heat left the gas and
internal energy remained same. The work done on
gas in Nm will be
(a) 300 Nm
(b) 300,000 Nm
(c) 30 Nm
(d) 3000 Nm
(e) 30,000 Nm.
Ans: b
88. The more effective way of increasing efficiency
of Carnot engine is to
(a) increase higher temperature
(b) decrease higher temperature
(c) increase lower temperature
(d) decrease lower temperature
(e) keep lower temperature constant.
Ans: d
89. Entropy change depends on
(a) heat transfer
(b) mass transfer
(c) change of temperature
(d) thermodynamic state
(e) change of pressure and volume.
Ans: a
90. For reversible adiabatic process, change in
entropy is
(a) maximum
(b) minimum
(c) zero
(d) unpredictable
(e) negative.
Ans: c
91. Isochoric process is one in which
(a) free expansion takes place
(b) very little mechanical work is done by the
system
(c) no mechanical work is done by the system
(d) all parameters remain constant
(e) mass and energy transfer do not take place.
Ans: c
92. According to first law of thermodynamics
(a) work done by a system is equal to heat
transferred by the system
(b) total internal energy of  a system during a
process remains constant
(c) internal energy, enthalpy and entropy during a
process remain constant
(d) total energy of a system remains constant
(e) entropy of a system remains constant.
Ans: d
93. Energy can neither be created nor destroyed but
can be converted from one form to other is inferred
from
(a) zeroth low of thermodynamic
(b) first law of thermodynamics
(c) second law to thermodynamics
(d) basic law of thermodynamics
(e) claussius statement.
Ans: b
94. First law of thermodynamics furnishes the
relationship between
(a) heat and work
(b) heat, work and properties of the system
(c) various properties of the system
(d) various thermodynamic processes
(e) heat and internal energy.
Ans: b
95. Change in enthalpy in a closed system is equal
to heat transferred if the reversible process takes
place at constant
(a) pressure
(b) temperature
(c) volume
(d) internal energy
(e) entropy.
Ans: a
96. In an isothermal process, the internal energy
(a) increases
(b) decreases
(c) remains constant
(d) first increases and then decreases
(e) first decreases and then increases.
Ans: c
97. Change in internal energy in a closed system is
equal to heat transferred if the reversible process
takes place at constant
(a) pressure
(b) temperature
(c) volume
(d) internal energy
(e) entropy.
Ans: c
98. According to first law of thermodynamics
(a) mass and energy are mutually convertible
(b) Carnot engine is most efficient
(c) heat and work are mutually convertible
(d) mass and light are mutually convertible
(e) heat flows from hot substance to cold
substance.
Ans: c
99. Total heat of a substance is also known as
(a) internal energy
(b) entropy
(c) thermal capacity
(d) enthalpy
(e) thermalconductance.
Ans: d
100. First law of thermodynamics
(a) enables to determine change in internal energy
of the system
(b) does not help to predict whether the system will
or not undergo a change
(c) does not enable to determine change in entropy
(d) provides relationship between heat, work and
internal energy
(e) all of the above.
Ans: e
101. Addition of heat at constant pressure to a gas
results in
(a) raising its temperature
(b) raising its pressure
(c) raising its volume
(d) raising its temperature and doing external work
(e) doing external work.
Ans: d
102. Carnot cycle has maximum efficiency for
(a) reversible engine
(b) irreversible engine
(c) new engine
(d) petrol engine
(e) diesel engine.
Ans: a
103. Measurement of temperature is based on
(a) thermodynamic properties
(b) zeroth law of thermodynamics
(c) first law of thermodynamics
(d) second law of thermodynamics
(e) joule's law.
Ans: b
104. Carnot cycle efficiency depends upon
(a) properties of the medium/substance used
(b) condition of engine
(c) working condition
(d) temperature range of operation
(e) effectiveness of insulating material around the
engine.
Ans: d
105. Carnot cycle efficiency is maximum when
(a) initial temperature is 0°K
(b) final temperature is 0°K
(c) difference between initial and final temperature
is 0°K
(d) final temperature is 0°C
(e) initial temperature is minimum possible.
Ans: b
106. An engine operates between temperatures of
900°Kandr2 and another engine between T2 and
400°K For both to do equal work, value of T2 will be
(a) 650°K
(b) 600°K
(c) 625°K
(d) 700°K
(e) 750°K.
Ans: a
107. If heat be exchanged in a reversible manner,
which of the following property of the working
substance will change accordingly
(a) temperature
(b) enthalpy
(c) internal energy
(d) entropy
(e) all of the above.
Ans: d
108. If a system after undergoing a series of
processes, returns to the initial state then
(a) process is thermodynamically in equilibrium
(b) process is executed in closed system cycle
(c) its entropy will change due to irreversibility
(d) sum of heat and work transfer will be zero
(e) no work will be done by the system.
Ans: d
109. Which of the following represents the perpetual
motion of the first kind
(a) engine with 100% thermal efficiency
(b) a fully reversible engine
(c) transfer of heat energy from low temperature
source to high temperature source
(d) a machine that continuously creates its own
energy
(e) production of energy by temperature differential
in sea water at different levels.
Ans:
110. An actual engine is to be designed having
same efficiency as the Carnot cycle. Such a
proposition is
(a) feasible
(b) impossible
(c) possible
(d) possible, but with lot of sophistications
(e) desirable.
Ans: d
112. A manufacturer claims to have a heat engine
capable of developing 20 h.p. by receiving heat input
of 400 kcal/mt and working between the
temperature limits of 227° C and 27° C. His claim is
(a) justified
(b) not possible
(c) may be possible with lot of sophistications
(d) cost will be very high
(e) theroretically possible.
Ans: b
113. In a Carnot cycle, heat is transferred at
(a) constant pressure
(b) constant volume
(c) constant temperature
(d) constant enthaply
(e) any one of the above.
Ans: c
114. A diathermic wall is one which
(a) prevents thermal interaction
(b) permits thermal interaction
(c) encourages thermal interaction
(d) discourages thermal interaction
(e) does not exist.
Ans: b
115. An adiabatic wall is one which
(a) prevents thermal interaction
(b) permits thermal interaction
(c) encourages thermal interaction
(d) discourages thermal interaction
(e) dos not exist.
Ans: a
116. The door of a running refrigerator inside a
room was left open. Which of the following
statements is correct?
(a) The room will be cooled to the temperature
inside the refrigerator.
(b) The room will be cooled very slightly.
(c) The room will be gradually warmed up.
(d) The temperature of the air in room will remain
unaffected.
(e) any one of above is possible depending on the
capacity.
Ans: c
117. Compressed air coming out from a punctured
football
(a) becomes hotter
(b) becomes cooler1
(c) remains at the same temperature
(d) may become hotter or cooler depend-ing upon
the humidity of the surround¬ing air
(e) attains atmospheric temperature.
Ans: b
118. Water contained in a beaker can be made to
boil by passing steam through it
(a) at atmospheric pressure
(b) at a pressure below the firuosphejric pressure
(c) at a pressure greater than atmospheric
pressure
(d) any pressure
(e) not possible.
Ans: c
119. During throttling process
(a) heat exchange does not take place
(b) no work is done by expanding steam
(c) there is no change of internal energy of steam
(d) all of the above
(e) entropy decreases.
Ans: d
120. The energy of molecular motion appears as
(a) heat
(b) potential energy
(c) surface tension
(d) friction
(e) increase in pressure.
Ans: a
121. A sudden fall in the barometer reading is a
sign of approaching
(a) fine weather
(b) rains
(c) storm
(d) cold wave
(e) hot wave.
Ans: c
122. The unit'of universal gas constant is
(a) watts/°K
(b) dynes/°C
(c) ergscm/°K
(d)erg/°K
(e) none of the above.
Ans: d
123. Calorie is a measure of
(a) specific heat
(b) quantity of heat
(c) thermal capacity
(d)entropy
(e) work.
Ans: b
124. I kgf/cm2 is equal to
(a) 760 mm Hg
(b) zero mm Hg
(c) 735.6 mm Hg
(d) 1 mm Hg
(e) lOOmmHg.
Ans: c
125. Barometric pressure is equal to
(a) 760 mm Hg
(b) zero mm Hg
(c) 735.6 mm Hg
(d) 1 mm Hg
(e) 100mm Hg.
Ans: a
126. One barometric pressure or 1 atmospheric
pressure is equal to
(a) 1 kgf/cnr2
(b) 1.033 kgf/cm2
(c) 0 kgf/cm2
(d) 1.0197 kgf/cm2
(e) 100 kgf/cm2.
Ans: b
127. The first law of thermodynamics is the law of
(a) conservation of mass
(b) conservation of energy
(c) conservation of momentum
(d) conservation of heat
(e) conservation of temperature.
Ans: b
128. A perpetual motion machine is
(a) a thermodynamic machine
(b) a non-thermodynamic machine
(c) a hypothetical machine
(d) a hypothetical machine whose opera-tion would
violate the laws of thermodynamics
(e) an inefficient machine.
Ans: d
129. Kelvin Planck's law deals with
(a) conservation of heat
(b) conservation of work
(c) conversion of heat into work
(d) conversion fo work into heat
(e) conservation of mass.
Ans: c
130. According to Clausis statement of second law
of thermodynamics
(a) heat can't be transferred from low temperature
source to high temperature source
(b) heat can be transferred for low temperature to
high temperature source by using refrigeration
cycle.
(c) heat can be transferred from low temperature to
high temperature source if COP of process is more
than unity
(d) heat can't be transferred from low temperature
to high temperature source without the aid of
external energy
(e) all of the above.
Ans: d
131. Thermal power plant works on
(a) Carnot cycle
(b) Joule cycle
(d) Rankine cycle
(d) Otto cycle
(e) Brayton cycle.
Ans: c
132. Which of the following is an irreversible cycle
(a) carnot
(b) Stirling
(c) ericsson
(d) all of the above
(e) none of the above.
Ans: e
133. Otto cycle consists of following four processes
(a) two isothermals and two isentropics
(b) two isentropics and two constant volumes
(c) two isentropics, one constant volume and one
constant pressure
(d) two isentropics and two constant pres-sures
(e) none of the above.
Ans: b
134. The efficiency of a Carnot engine depends on
(a) working substance
(b) design of engine
(c) size of engine
(d) type of fuel fired
(e) temperatures of source and sink.
Ans: e
135. For same compression ratio and for same heat
added
(a) Otto cycle is more efficient than Diesel cycle
(b) Diesel cycle is more efficient than Otto cycle
(c) efficiency depends on other factors
(d) both Otto and Diesel cycles are equally efficient
(e) none of the above.
Ans: a
136. The efficiency of Carnot cycle is maximum for
(a) gas engine
(b) well lubricated engine
(c) petrol engine
(d) steam engine
(e) reversible engine.
Ans: e
137. Carnot cycle is
(a) a reversible cycle (ft) an irreversible cycle
(c) a semi-reversible cycle
(d) a quasi static cycle
(e) an adiabatic irreversible cycle.
Ans: a
138. Diesel cycle consists of following four
processes
(a) two isothermals and two isentropics
(b) two isentropics, and two constant volumes.
(c) two isentropics, one constant volume and one
constant pressure
(d) two isentropics and two constant pressures
(e) none of the above.
Ans: c
139. If both Stirling and Carnot cycles operate within
the same temperature limits, then efficiency of
Stirling cycle as compared to Carnot cycle
(a) more
(b) less
(c) equal
(d) depends on other factors
(e) none of the above.
Ans: c
140. Stirling and Ericsson cycles are
(a) reversible cycles
(b) irreversible cycles
(c) quasi-static cycles
(d) semi-reversible cycles
(e) adiabatic irreversible cycles.
Ans: a
141. A cycle consisting of two adiabatics and two
constant pressure processes is known as
(a) Otto cycle
(b) Ericsson cycle
(c) Joule cycle
(d) Stirling cycle
(e) Atkinson cycle.
Ans: c
142. Reversed joule cycle is called
(a) Carnot cycle
(b) Rankine cycle
(c) Brayton cycle
(d) Bell Coleman cycle
(e) Dual cycle.
Ans: c
143. Brayton cycle consists' of following four
processes
(a) two isothermals and two isentropics
(b) two isentropics and two constant volumes
(c) two isentropics, one constant volume and one
constant pressure
(d) two isentropics and two constant pres-sures
(e) none of the above.
Ans: d
144. Which of the following cycles is not a
reversible cycle
(a) Carnot
(b) Ericsson
(c) Stirling
(d) Joule
(e) none of the above.
Ans: e
145. The cycle in which heat is supplied at constant
volume and rejected at constant pressure is known
as
(a) Dual combustion cycle
(b) Diesel cycle
(c) Atkinson cycle
(d) Rankine cycle
(e) Stirling cycle.
Ans: c
146. The efficiency of Diesei cycle with decrease in
cut off
(a) increases
(b) decreases
(c) remains unaffected
(d) first increases and then decreases
(e) first decreases and then increases.
Ans: a
147. Which of the following cycles has maximum
efficiency
(a) Rankine
(b) Stirling
(c) Carnot
(d) Brayton
(e) Joule.
Ans: c
148. The ideal efficiency of a Brayton cycle without
regeneration with increase ni pressure ratio will
(a) increase
(b) decrease
(c) remain unchanged
(d) increase/decrease depending  on application
(e) unpredictable.
Ans: a
149. The ideal efficiency of a Brayton cycle with
regeneration, with increase in pressure ratio will
(a) increase
(b) decrease
(c) remain unchanged
(d) increase/decrease depending on ap-plication
(e) unpredictable. "
Ans: b
150. The following cycle is used for air craft
refrigeration
(a) Brayton cycle
(b) Joule cycle
(c) Carnot cycle
(d) Bell-Coleman cycle
(e) Reversed-Brayton cycle.
Ans: e
151. Gas turbine cycle consists of
(a) two isothermals and two isentropics
(b) two isentropics and two constant volumes
(c) two isentropics, one constant volume and one
constant pressure
(d) two isentropics and two constant pressures
(e) none of the above.
Ans: d
152. The thermodynamic difference between a
Rankine cycle working with saturated steam and the
Carnot cycle is that
(a) carnot cycle can't work with saturated steam
(b) heat is supplied to water at temperature below
the maximum temperature of the cycle
(c) a rankine cycle receives heat at two places
(d) rankine cycle is hypothetical
(e) none of the above.
Ans: b

Thursday 7 August 2014

Basic Thermodynamic

Thermodynamic System

The study of thermodynamics considers the basic subject of the analysis what is called a system. In
general, a system can be defined solely as the part of the universe that the research or study focus the
attention. The previous understanding of system divides the universe into two parts, the system and
the surroundings . Thus, the surroundings is everything in the universe outside of the system.
Macroscopic Point of View
The thermodynamics study of a system can be described in terms of general quantities such as the
system composition (chemical composition in many cases), volume, pressure, and temperature. This is the macroscopic point of view of a thermodynamic system. Thus, the macroscopic point of view of a thermodynamic system refers to the large scale properties of the system.
Microscopic Point of View
The microscopic study of thermodynamic system is based on the formulations of statistical mechanics. Under this formalism, the thermodynamic system is considered to be formed by a very large number of molecules, N , where the individual molecules are characterized by six independent parameters. Of the six independent parameters, three are the position coordinates of the molecule at any instant of time; and, the remaining three parameters are the velocity coordinates of the molecule. The molecules of the thermodynamic system can interact with  each other through simple collisions or through forces produced by their particular fields. These forces are especially important when they are of the magnetic or electric nature. The thermodynamic system is analyzed in terms of the possible energy states accessible to the individual molecules. After measuring macroscopic quantities associated to the thermodynamic system, the value of the macroscopic parameters are a reflection of the equilibrium state of the thermodynamic system as obtained from the probabilistic analysis of the
possible microscopic individual energy states of the molecules. The probabilistic analysis of the possible states of the individual molecules of the system  determines all the possible states of the
thermodynamic system; from those, the state with the highest probability is called the equilibrium
state. In the study of thermodynamic systems, the population (number of molecules) of the different
molecular energy states is the foremost problem to be solved.
In many cases, to validate the probabilistic approach to the study of thermodynamic systems the  system is considered part of an ensemble of systems. An ensemble of system is a large number of similar system where the system under study is a part.

Mechanical and Thermodynamic Coordinates. Mechanical coordinates are associated to the external analysis of the position and velocity of a complete system such as a rigid body. Based on the mechanical coordinates of the system, the potential and kinetic energies of the system can be calculated. The potential and kinetic energies are called the mechanical or external energy of the system, On the other side, macroscopic quantities determining the internal state of the system are called thermodynamic coordinates . The thermodynamic quantities are used to establish the internal energy of the system. A system is a thermodynamic system, if it can be described in terms of the thermodynamic coordinates.
Thermal Equilibrium
If for a given state of a thermodynamic system, the set of thermodynamic coordinates have a definite
constant value for unchanged external conditions, the state of the system is an equilibrium state. An
individual system reaches the equilibrium state when under unchanged external conditions the thermodynamic coordinates describing the system have a defined constant value. On a multiple systems case, when two systems are in contact with each other, they can be in contact by way of a wall that can be perfectly adiabatic all the way through a wall that is perfectly diathermic .
Adiabatic Walls
A wall is called adiabatic if the wall does not permit the transfer of energy (heat) ( add link to heat) between the systems. Under this conditions, the two systems can maintain their own equilibrium state without interfering with each other. Thus, the thermodynamics coordinates associated with each other are unchanged because of the contact between the two systems. Therefore, the two systems can coexist for any value of the thermodynamics variables associated to the equilibrium state of the individual systems.
Materials such as concrete, asbestos, and styrofoam represent a good approximation of adiabatic walls.
Diathermic Walls
A diathermic wall allows the exchange of energy between the two systems (thermal interaction). This exchange of energy produces a change in the thermodynamic coordinates of the two systems until an  equilibrium state between the two systems is obtained. When the two systems have reached an  equilibrium state, the two systems are in thermal equilibrium . Thus, thermal equilibrium is achieved by two or more systems when in contact through diathermic walls, if all the thermodynamic coordinates of the systems reach determined constant values characteristic of the individual system equilibrium states.
Zero Law
Experimentally, it can be seen that thermodynamic  systems in equilibrium satisfies the fallowing transitivity rule:
"If the thermodynamic system A is in thermal equilibrium with the thermodynamic system B, and
the thermodynamic system B is in thermal equilibrium with the thermodynamic system C; then, the thermodynamic system A is in thermal equilibrium with the thermodynamic system C."

The previous statement is called the zero law of thermodynamic. The name is originated from the fact that after the first and second law of thermodynamic were established, it was concluded that the  revious statement was implicitly assumed to be valid without a formal foundation. A simple  experiment that illustrate the scope of the Zero Law of Thermodynamic is described as follow:

In the schematic drawing on the left, between systems A and B there is an adiabatic wall that prevent  the thermal exchange between the two systems. At the same time, both systems are in contact with a third system, C, through diathermic walls that allow the thermal exchange. Thus, the thermal exchanges are possible between systems A and C, or between systems B and C. Nevertheless, the thermal exchange between systems A and B is still prevented by the adiabatic wall. In order to prevent the thermal exchange between the systems and the surroundings, the three systems are enclosed by adiabatic walls. After maintaining the experimental configuration described above for sufficient time, it is encountered that systems A and B reach thermal equilibrium with system C. That is, there is not more thermal exchange between systems A and C or between systems B and C. Remember that the adiabatic wall is preventing the thermal exchange between systems A and B. At this point, system C can be removed from contacting systems A and B. In addition, the adiabatic wall between systems A and B is replaced by a diathermic wall. As mentioned before, this kind of wall allows the thermal exchange between the systems in contact.
However, the experimental result is that there is not thermal exchange between the two systems, A and B. There is not net thermal exchange when the systems in contact have reached thermal equilibrium. Therefore, systems A and B reached equilibrium between them when they reached equilibrium with system C. Thus, if system A is in thermal equilibrium with system C and system C is in thermal equilibrium with system B; then, system A is in thermal equilibrium with system B which is exactly the postulated of the Zero Law of thermodynamics.

Thursday 24 July 2014

Gas Power Cycle

Introduction:
An important application of thermodynamics is the analysis of power cycles through which the  energy absorbed as heat can be continuously converted into mechanical work. A thermodynamic analysis of the heat engine cycles provides valuable information regarding the design of new cycles  or for improving the existing cycles.
Classification of Cycles:
The purpose of a thermodynamic cycle is either to produce power, or to produce refrigeration/pumping of heat. Therefore, the cycles are broadly classified as follows:
(a) Heat engine or power cycles.
(b) Refrigeration/heat pump cycles.
Any thermodynamic cycle is essentially a closed cycle in which, the working substance undergoes a series of processes and is always brought back to the initial state. However, some of the power cycles operate on open cycle. It means that the working substance is taken into the unit from the atmosphere at one end and is discharged into the atmosphere after undergoing a series of processes at the other end. The following are illustrations of heat engines operating on open cycle:
(i) Petrol and diesel engines in which the air and fuel are taken into the engine from a fuel tank and products of combustion are exhausted into the atmosphere.
(ii) Steam locomotives in which the water is taken in the boiler from a tank and steam is exhausted into the atmosphere. Essentially, such devices do not form a cycle. However, they can be analyzed by adding an imaginary processes to bring the state of the working substance, thus completing a cyclic.

Note that the terms closed cycle and open cycle used here do not mean closed system cycle and open system cycle. In fact, the processes both in closed and open cycles could either be closed or open system processes.

Different types of working fluids are employed in the power plants. The nature of the working fluids can be classified into two groups: vapours and gases.
The power cycles are accordingly classified into two groups as:
(1) Vapour power cycles in which the working fluid undergoes a phase change during the cyclic process.
(2) Gas power cycles in which the working fluid does not undergo any phase change.
In the thermodynamic analysis of power cycles, our chief interest lies in estimating the energy conversion efficiency or the thermal efficiency. The thermal efficiency of a heat engine is defined as the ratio of the network delivered to the energy absorbed as heat.
Analysis of Cycles:
In air standard analysis, air is considered as the working medium. The analysis is carried out with the following assumptions.
Assumptions:
(i) The working substance consists of a fixed mass of air and behaves as a perfect gas. The closed system is considered which under goes a cycle process. Therefore, there are no intake or exhaust process.
(ii) The combustion process is replaced by an equivalent heat addition process form an external source. Thus there is no change in the chemical equilibrium of the working fluid and also composition.
(iii) There is no exhaust process; this is replaced by an equivalent heat rejection process.
(iv) Compression and expansion processes in the cycle are considered as reversible adiabatic process.
(v) The specific heats Cp and Cv of air do not vary with temperature.